diff --git a/pgtype/qchar.go b/pgtype/qchar.go
index fc40a5b2c..3de0b01fc 100644
--- a/pgtype/qchar.go
+++ b/pgtype/qchar.go
@@ -64,6 +64,8 @@ func (QCharCodec) PlanScan(m *Map, oid uint32, format int16, target any) ScanPla
 			return scanPlanQcharCodecByte{}
 		case *rune:
 			return scanPlanQcharCodecRune{}
+		case *string:
+			return scanPlanQcharCodecString{}
 		}
 	}
 
@@ -114,6 +116,26 @@ func (scanPlanQcharCodecRune) Scan(src []byte, dst any) error {
 	return nil
 }
 
+type scanPlanQcharCodecString struct{}
+
+func (scanPlanQcharCodecString) Scan(src []byte, dst any) error {
+	if src == nil {
+		return fmt.Errorf("cannot scan NULL into %T", dst)
+	}
+
+	if len(src) > 1 {
+		return fmt.Errorf(`invalid length for "char": %v`, len(src))
+	}
+
+	p := dst.(*string)
+	// Copy the raw byte so the result matches the text-format *string scan path
+	// (string(src)) byte-for-byte. string(src[0]) would instead UTF-8-encode the
+	// byte as a code point, diverging for byte values >= 128.
+	*p = string(src)
+
+	return nil
+}
+
 func (c QCharCodec) DecodeDatabaseSQLValue(m *Map, oid uint32, format int16, src []byte) (driver.Value, error) {
 	if src == nil {
 		return nil, nil
diff --git a/pgtype/qchar_test.go b/pgtype/qchar_test.go
index 9de7d5544..1d294074c 100644
--- a/pgtype/qchar_test.go
+++ b/pgtype/qchar_test.go
@@ -5,6 +5,7 @@ import (
 	"math"
 	"testing"
 
+	"github.com/jackc/pgx/v5/pgtype"
 	"github.com/jackc/pgx/v5/pgxtest"
 )
 
@@ -22,3 +23,71 @@ func TestQcharTranscode(t *testing.T) {
 	// Can only test with known OIDs as rune and byte would be considered numbers.
 	pgxtest.RunValueRoundTripTests(context.Background(), t, defaultConnTestRunner, pgxtest.KnownOIDQueryExecModes, `"char"`, tests)
 }
+
+// TestQcharCodecPlanScanString is a regression test for https://github.com/jackc/pgx/issues/2314.
+//
+// Scanning a "char" column (OID 18) into *string used to succeed in TextFormat but
+// fail in BinaryFormat with "cannot scan char (OID 18) in binary format into *string".
+// Both formats must now produce the same result.
+func TestQcharCodecPlanScanString(t *testing.T) {
+	m := pgtype.NewMap()
+
+	for _, tt := range []struct {
+		name   string
+		format int16
+	}{
+		{"text", pgtype.TextFormatCode},
+		{"binary", pgtype.BinaryFormatCode},
+	} {
+		t.Run(tt.name, func(t *testing.T) {
+			var s string
+			plan := m.PlanScan(pgtype.QCharOID, tt.format, &s)
+			if plan == nil {
+				t.Fatalf("PlanScan returned nil plan for *string in %s format", tt.name)
+			}
+			if err := plan.Scan([]byte{'a'}, &s); err != nil {
+				t.Fatalf("Scan failed in %s format: %v", tt.name, err)
+			}
+			if s != "a" {
+				t.Fatalf("Scan result mismatch in %s format: got %q want %q", tt.name, s, "a")
+			}
+		})
+	}
+
+	// Empty src must produce empty string (mirrors *byte / *rune zero-value behavior).
+	t.Run("empty-binary", func(t *testing.T) {
+		var s string = "x"
+		plan := m.PlanScan(pgtype.QCharOID, pgtype.BinaryFormatCode, &s)
+		if err := plan.Scan([]byte{}, &s); err != nil {
+			t.Fatalf("Scan failed: %v", err)
+		}
+		if s != "" {
+			t.Fatalf("empty src: got %q want %q", s, "")
+		}
+	})
+
+	// 0xC8 (200): a byte >= 128. Both formats must yield the raw 1-byte string
+	// "\xc8", not the 2-byte UTF-8 encoding "\xc3\x88". This is the case that
+	// catches string(src[0]) UTF-8-encoding the byte instead of copying it.
+	t.Run("non-ascii-byte", func(t *testing.T) {
+		for _, format := range []int16{pgtype.TextFormatCode, pgtype.BinaryFormatCode} {
+			var s string
+			plan := m.PlanScan(pgtype.QCharOID, format, &s)
+			if err := plan.Scan([]byte{0xC8}, &s); err != nil {
+				t.Fatalf("format %d: scan failed: %v", format, err)
+			}
+			if s != "\xc8" {
+				t.Fatalf("format %d: got %q (% x) want %q", format, s, s, "\xc8")
+			}
+		}
+	})
+
+	// Multi-byte src is an invalid "char" payload and must error.
+	t.Run("too-long", func(t *testing.T) {
+		var s string
+		plan := m.PlanScan(pgtype.QCharOID, pgtype.BinaryFormatCode, &s)
+		if err := plan.Scan([]byte("ab"), &s); err == nil {
+			t.Fatalf("expected error for 2-byte src, got nil (s=%q)", s)
+		}
+	})
+}